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Stable radicals – molecules with odd electrons which are sufficiently long lived to be studied or isolated using conventional techniques – have enjoyed a long history and are of current interest for a broad array of fundamental and applied reasons, for example to study and drive novel chemical reactions, in the development of rechargeable batteries or the study of free radical reactions in the body. In Stable Radicals: Fundamentals and Applied Aspects of Odd-Electron Compounds a team of international experts provide a broad-based overview of stable radicals, from the fundamental aspects of specific classes of stable neutral radicals to their wide range of applications including synthesis, materials science and chemical biology. Topics covered include: triphenylmethyl and related radicals polychlorinated triphenylmethyl radicals: towards multifunctional molecular materials phenalenyls, cyclopentadienyls, and other carbon-centered radicals the nitrogen oxides: persistent radicals and van der Waals complex dimers nitroxide radicals: properties, synthesis and applications the only stable organic sigma radicals: di-tert-alkyliminoxyls. delocalized radicals containing the hydrazyl [R2N-NR] unit metal-coordinated phenoxyl radicals stable radicals containing the thiazyl unit: synthesis, chemical, and materials properties stable radicals of the heavy p-block elements application of stable radicals as mediators in living-radical polymerization nitroxide-catalyzed alcohol oxidations in organic synthesis metal-nitroxide complexes: synthesis and magneto-structural correlations rechargeable batteries using robust but redox-active organic radicals spin labeling: a modern perspective functional in vivo EPR spectroscopy and imaging using nitroxides and trityl radicals biologically relevant chemistry of nitroxides Stable Free Radicals: Fundamentals and Applied Aspects of Odd-Electron Compounds is an essential guide to this fascinating area of chemistry for researchers and students working in organic and physical chemistry and materials science.

Covers the most advanced computational and experimental methods for studying carbon-centered radical intermediates With its focus on the chemistry of carbon-centered radicals and radical cations, this book helps readers fully exploit the synthetic utility of these intermediates in order to prepare fine chemicals and pharmaceutical products. Moreover, it helps readers better understand their role in complex atmospheric reactions and biological systems. Thoroughly up to date, the book highlights the most advanced computational and experimental methods available for studying and using these critically important intermediates. Carbon-Centered Free Radicals and Radical Cations begins with a short history of the field of free radical chemistry, and then covers: A discussion of the relevant theory Mechanistic chemistry, with an emphasis on synthetic utility Molecular structure and mechanism, focusing on computational methods Spectroscopic investigations of radical structure and kinetics, including demonstrations of spin chemistry techniques such as CIDNP and magnetic field effects Free radical chemistry in macromolecules Each chapter, written by one or more leading experts, explains difficult concepts clearly and concisely, with references to facilitate further investigation of individual topics. The authors were selected in order to provide insight into a broad range of topics, including small molecule synthesis, polymer degradation, computational chemistry as well as highly detailed experimental work in the solid, liquid, and gaseous states. This volume is essential for students or researchers interested in building their understanding of the role of carbon-centered radical intermediates in complex systems and how they may be used to develop a broad range of useful products.

Protestant Christianity began with one stubborn monk in 1517. Now it covers the globe and includes almost a billion people. On the 500th anniversary of Luther’s theses, a global history of the revolutionary faith that shaped the modern world.Five hundred years ago an obscure monk challenged the authority of the pope with a radical vision of what Christianity could be. The revolution he set in motion inspired one of the most creative and destructive movements in human history. It has toppled governments, upended social norms, and transformed millions of people’s understanding of their relationship with God. In this dazzling global history of innovation and change, Alec Ryrie makes the case that Protestants made the modern world.‘Protestants’ introduces us to the men and women who defined and redefined this quarrelsome faith. Some turned to their newly accessible Bibles to justify bold acts of political opposition; others to support a new understanding of who they were and what they could and should do. Above all, Protestants were willing to fight for their beliefs. If you look at the great confrontations of the last five centuries, you will find Protestants defining the debate on both sides: for and against colonialism, slavery, fascism, communism, women’s rights, and more. Protestants have also fought among themselves. What unites them all is their passion for God and a vital belief in the principle of self-determination. Protestants are people who love God and take on the world.Protestants have set out for all four corners of the globe, embarking on courageous journeys into the unknown to set up new communities and experiment with new systems of government. Protestants created America and defined its special brand of entrepreneurial diligence, but they also can be found behind the brutality of apartheid and Nazi Germany. They are resourceful innovators, making new converts every day in China, Africa, and Latin America. Whether you are yourself a Protestant, or even a Christian, you live in a world, and are guided by principles and ideas, shaped by Protestants.

Terrorism, mass uprisings, and political extremism are in the news every day. It is no coincidence that these phenomena come together at the beginning of a new era. Radicals, Revolutionaries, and Terrorists provides a comprehensive survey of the intersection of radical social movements and political violence. The book considers eight essential questions for understanding radicalism, including its origins, dynamics, and outcomes. Ranging across the globe from the 1500s to the present, the book examines cases as diverse as nineteenth-century anarchists, the Nazis, Che Guevara, the Weather Underground, Chechen insurgents, the Earth Liberation Front, Al-Qaeda, and the Arab Spring. Throughout, Colin J. Beck connects these cases to key social movements literature to demonstrate how using multiple areas of research results in better explanations. Radicals, Revolutionaries, and Terrorists is an essential companion for understanding the challenges facing governments and societies today. Its engaging style and original approach make it indispensable for students and scholars across the social sciences who are interested in social movements.