Найти книгу: "Homogeneous Catalysts"

This first book to illuminate this important aspect of chemical synthesis improves the lifetime of catalysts, thus reducing material and saving energy, costs and waste. The international panel of expert authors describes the studies that have been conducted concerning the way homogeneous catalysts decompose, and the differences between homogeneous and heterogeneous catalysts. The result is a ready reference for organic, catalytic, polymer and complex chemists, as well as those working in industry and with/on organometallics.

Authored by one of the world's leading organic chemists, this authoritative reference provides an overview of basic strategies in directed evolution and introduces common gene mutagenesis, screening and selection methods. Throughout the text, emphasis is placed on methodology development to maximize efficiency, reliability and speed of the experiments and to provide guidelines for efficient protein engineering. Professor Reetz highlights the application of directed evolution experiments to address limitations in the field of enzyme selectivity, substrate scope, activity and robustness. He critically reviews recent developments and case studies, takes a look at future applications in the field of organic synthesis, and concludes with lessons learned from previous experiments.

Demystifies the largest volume manmade synthetic polymer by distillingthe fundamentals of what polyethylene is, how it's made and processed,and what happens to it after its useful life is over. Endorsement for Introduction to Industrial Polyethylene «I found this to be a straightforward, easy-to-read, and useful introductory text on polyethylene, which will be helpful for chemists, engineers, and students who need to learn more about this complex topic. The author is a senior polyethylene specialist and I believe we can all benefit from his distillation of knowledge and insight to quickly grasp the key learnings.» —R.E. King III; Ciba Corporation (part of the BASF group) Jargon used in industrial polyethylene technology can often be bewildering to newcomers. Introduction to Industrial Polyethylene educates readers on terminology commonly used in the industry and demystifies the chemistry of catalysts and cocatalysts employed in the manufacture of polyethylene. This concise primer reviews the history of polyethylene and introduces basic features and nomenclatures for this versatile polymer. Catalysts and cocatalysts crucial to the production of polyethylene are discussed in the first few chapters. Latter chapters provide an introduction to the processes used to manufacture polyethylene and discuss matters related to downstream applications of polyethylene such as rheology, additives, environmental issues, etc. Providing industrial chemists and engineers a valuable reference tool that covers fundamental features of polyethylene technology, Introduction to Industrial Polyethylene: Identifies the fundamental types of polyethylene and how they differ. Lists markets, key fabrication methods, and the major producers of polyethylene. Provides biodegradable alternatives to polyethylene. Describes the processes used in the manufacture of polyethylene. Includes a thorough glossary, providing definitions of acronyms and abbreviations and also defines terms commonly used in discussions of production and properties of polyethylene. Concludes with the future of industrial polyethylene.

This long-awaited reference source is the first book to focus on this important and hot topic. As such, it provides examples from a wide array of fields where catalyst design has been based on new insights and understanding, presenting such modern and important topics as self-assembly, nature-inspired catalysis, nano-scale architecture of surfaces and theoretical methods. With its inclusion of all the useful and powerful tools for the rational design of catalysts, this is a true «must have» book for every researcher in the field.

Catalytic asymmetric synthesis has been one of the most active research areas in chemistry (Nobel Prize in 2001). The development of efficient chiral catalysts plays a crucial role in asymmetric catalysis. Although many chiral ligands/catalysts have been developed in the past decades, the most efficient catalysts are derived from a few core structures, called «privileged chiral catalysts». This ultimate «must have» and long awaited reference for every chemist working in the field of asymmetric catalysis starts with the core structure of the catalysts, explaining why a certain ligand or catalyst is so successful. It describes in detail the history, the basic structural characteristics, and the applications of these «privileged catalysts». This novel presentation provides readers with a much deeper insight into the topic and makes it a must-have for organic chemists, catalytic chemists, chemists working with/on organometallics, chemists in industry, and libraries. From the contents: * BINAP * Bisphosphacycles – From DuPhos and BPE to a Diverse Set of Broadly Applied Ligands * Josiphos Ligands: From Discovery to Technical Applications * Chiral Spiro Ligands * Chiral Bisoxazoline Ligands * PHOX Ligands * Chiral Salen Complexes * BINOL * TADDOLate Ligands * Cinchona Alkaloids * Proline Derivatives

Over the last 60 years the increasing knowledge of transition metal chemistry has resulted in an enormous advance of homogeneous catalysis as an essential tool in both academic and industrial fields. Remarkably, phosphorus(III) donor ligands have played an important role in several of the acknowledged catalytic reactions. The positive effects of phosphine ligands in transition metal homogeneous catalysis have contributed largely to the evolution of the field into an indispensable tool in organic synthesis and the industrial production of chemicals. This book aims to address the design and synthesis of a comprehensive compilation of P(III) ligands for homogeneous catalysis. It not only focuses on the well-known traditional ligands that have been explored by catalysis researchers, but also includes promising ligand types that have traditionally been ignored mainly because of their challenging synthesis. Topics covered include ligand effects in homogeneous catalysis and rational catalyst design, P-stereogenic ligands, calixarenes, supramolecular approaches, solid phase synthesis, biological approaches, and solubility and separation. Ligand families covered in this book include phosphine, diphosphine, phosphite, diphosphite, phosphoramidite, phosphonite, phosphinite, phosphole, phosphinine, phosphinidenene, phosphaalkenes, phosphaalkynes, P-chiral ligands, and cage ligands. Each ligand class is accompanied by detailed and reliable synthetic procedures. Often the rate limiting step in the application of ligands in catalysis is the synthesis of the ligands themselves, which can often be very challenging and time consuming. This book will provide helpful advice as to the accessibility of ligands as well as their synthesis, thereby allowing researchers to make a more informed choice. Phosphorus(III) Ligands in Homogeneous Catalysis: Design and Synthesis is an essential overview of this important class of catalysts for academic and industrial researchers working in catalyst development, organometallic and synthetic chemistry.