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The recent financial crisis has highlighted the need for better valuation models and risk management procedures, better understanding of structured products, and has called into question the actions of many financial institutions. It has become commonplace to blame the inadequacy of credit risk models, claiming that the crisis was due to sophisticated and obscure products being traded, but practitioners have for a long time been aware of the dangers and limitations of credit models. It would seem that a lack of understanding of these models is the root cause of their failures but until now little analysis had been published on the subject and, when published, it had gained very limited attention. Credit Models and the Crisis is a succinct but technical analysis of the key aspects of the credit derivatives modeling problems, tracing the development (and flaws) of new quantitative methods for credit derivatives and CDOs up to and through the credit crisis. Responding to the immediate need for clarity in the market and academic research environments, this book follows the development of credit derivatives and CDOs at a technical level, analyzing the impact, strengths and weaknesses of methods ranging from the introduction of the Gaussian Copula model and the related implied correlations to the introduction of arbitrage-free dynamic loss models capable of calibrating all the tranches for all the maturities at the same time. It also illustrates the implied copula, a method that can consistently account for CDOs with different attachment and detachment points but not for different maturities, and explains why the Gaussian Copula model is still used in its base correlation formulation. The book reports both alarming pre-crisis research and market examples, as well as commentary through history, using data up to the end of 2009, making it an important addition to modern derivatives literature. With banks and regulators struggling to fully analyze at a technical level, many of the flaws in modern financial models, it will be indispensable for quantitative practitioners and academics who want to develop stable and functional models in the future.

This book presents a balance of theoretical considerations and practical problem solving of electrochemical impedance spectroscopy. This book incorporates the results of the last two decades of research on the theories and applications of impedance spectroscopy, including more detailed reviews of the impedance methods applications in industrial colloids, biomedical sensors and devices, and supercapacitive polymeric films. The book covers all of the topics needed to help readers quickly grasp how to apply their knowledge of impedance spectroscopy methods to their own research problems. It also helps the reader identify whether impedance spectroscopy may be an appropriate method for their particular research problem. This includes understanding how to correctly make impedance measurements, interpret the results, compare results with expected previously published results form similar chemical systems, and use correct mathematical formulas to verify the accuracy of the data. Unique features of the book include theoretical considerations for dealing with modeling, equivalent circuits, and equations in the complex domain, review of impedance instrumentation, best measurement methods for particular systems and alerts to potential sources of errors, equations and circuit diagrams for the most widely used impedance models and applications, figures depicting impedance spectra of typical materials and devices, extensive references to the scientific literature for more information on particular topics and current research, and a review of related techniques and impedance spectroscopy modifications.

This book introduces readers interested in the field of X-ray Photoelectron Spectroscopy (XPS) to the practical concepts in this field. The book first introduces the reader to the language and concepts used in this field and then demonstrates how these concepts are applied. Including how the spectra are produced, factors that can influence the spectra (all initial and final state effects are discussed), how to derive speciation, volume analysed and how one controls this (includes depth profiling), and quantification along with background substraction and curve fitting methodologies. This is presented in a concise yet comprehensive manner and each section is prepared such that they can be read independently of each other, and all equations are presented using the most commonly used units. Greater emphasis has been placed on spectral understanding/interpretation. For completeness sake, a description of commonly used instrumentation is also presented. Finally, some complementary surface analytical techniques and associated concepts are reviewed for comparative purposes in stand-alone appendix sections.

This text offers an open-learning approach to Raman spectroscopy providing detail on instrumentation, applications and discussions questions throughout the book. It provides a valuable guide to assist with teaching Raman spectroscopy which is gaining attention in (analytical) chemistry, and as a consequence, teaching programs have followed. Today, education in Raman spectroscopy is often limited to theoretical aspects (e.g. selection rules), but practical aspects are usually disregarded. With these course notes, the author hopes to fill this gap and include information about Raman instrumentation and how it is interpreted. Provides a user-friendly text that tackles the theoretical background, and offers everyday tips for common practice Raman instrumentation and practical aspects, which are sometimes overlooked, are covered Appropriate for students, and includes summaries, text boxes, illustrating the ideas with examples from research literature or providing background information or links with other courses Written with an open-learning approach, this book will be ideal for use as a self-study guide or as the basis of a taught course with discussion and self-assessment questions throughout the text Includes a comprehensive bibliography to guide the reader to more specialized texts and sources.

Computational spectroscopy is a rapidly evolving field that is becoming a versatile and widespread tool for the assignment of experimental spectra and their interpretation as related to chemical physical effects. This book is devoted to the most significant methodological contributions in the field, and to the computation of IR, UV-VIS, NMR and EPR spectral parameters with reference to the underlying vibronic and environmental effects. Each section starts with a chapter written by an experimental spectroscopist dealing with present challenges in the different fields; comprehensive coverage of conventional and advanced spectroscopic techniques is provided by means of dedicated chapters written by experts. Computational chemists, analytical chemists and spectroscopists, physicists, materials scientists, and graduate students will benefit from this thorough resource.