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Designed for practitioners of organic synthesis, this book helps chemists understand and take advantage of rearrangement reactions to enhance the synthesis of useful chemical compounds. Provides ready access to the genesis, mechanisms, and synthetic utility of rearrangement reactions Emphasizes strategic synthetic planning and implementation Covers 20 different rearrangement reactions Includes applications for synthesizing compounds useful as natural products, medicinal compounds, functional materials, and physical organic chemistry

The book consists of a brief introduction, a foreward provided by professor Danishefsky of Columbia University, and about 14 – 16 chapters, each written by one or two eminent scholars/authors describing their recent research in the area of either domino reactions or intramolecular rearrangements in carbohydrate chemistry. Three or four chapters will be reviews. The domino (cascade, tandem) reactions are always intramolecular. They are usually very fast, clean and offer highly complex structures in a one pot process. Intramolecular rearrangements offer very similar advantages and often lead to highly complex products as well. Although many recently isolated carbohydrates fulfill various sophisticated functions, their structures are often very complex. The editors cover the broadest scope of novel methodologies possible. All the synthetic and application aspects of domino/cascade reactions are explored in this book. A second theme that will be covered is intramolecular rearrangement, which is also fast, stereoselective, and often constitutes one or more steps of domino /cascade process. Selected examples of intramolecular rearrangements are presented. Together, both processes offer an elegant and convenient approach to the synthesis of many complex molecules, which are normally difficult to synthesize via alternative routes. It appears that domino and intramolecular rearrangements are ideally suited to synthesize certain specific modified monosaccharides. What is particularly important is that both processes are intermolecular and almost always yield products with very well-defined stereochemistry. This high definition is absolutely crucial when synthesizing advanced, modified mono and oligosaccharides. The choice of contributors reflects an emphasis on both therapeutic and pharmacological aspects of carbohydrate chemistry.

Move over Brad Pitt. Take a hike George Clooney. On your way Prince Harry. Give us Mark Darcy, King Aragorn and Edward Cullen instead.Have you met your book boyfriend yet?In WITHER 16-year-old Rhine Ellery is kidnapped and sold as a bride to Linden, a rich young man with a dying wife. Even though he is kind to her, Rhine is desperate to escape her gilded cage. With the help of Gabriel, a servant she is growing dangerously attracted to, Rhine attempts to break free, in what little time she has left. The Handmaid’s Tale for a new generationIn WAIT FOR YOU, a New York Times #1, Avery knows she should stay away from Cam Hamilton: he might be the hottest guy on campus but she really doesn’t need that sort of drama right now. Love is best left in the past – along with her troubles. But sometimes, the last thing that you want is just the thing you need…In New York Times bestseller, THE EDGE OF NEVER, twenty-year-old Camryn has always known that she wants a life less ordinary. But when tragedy strikes, she boards the next bus leaving town, destination unknown. On a journey of self-discovery, she meets another lost soul: Andrew Parrish, who harbours his own dark secrets… Andrew shows Camryn what it’s like to live by your own rules and how good it feels to give in to your deepest desires. But the dark shadow of Andrew’s secret is looming. Will it push them together – or tear them apart forever?

Ten hot greedy girl stories about women who love to be the centre of attention.‘My Boyfriend’s Boyfriends’ features original group sex erotica from Primula Bond, Janine Ashbless, Lisette Ashton, Penny Birch and many more. Another hot short story collection from Mischief Books.When Sara entertains her husband’s friends, she makes every jaw drop, but that’s not all that goes down in a crowded room.In a swingers club, Helen wants to enter a special space and accept all of the excessive pleasures on offer inside it.Penny takes part in a glory-hole competition and gets more than she bargained for.Smoking hot erotica stories where size and numbers matter.Other hot short story collections from Mischief include:Sex and the Stranger: A Collection of Casual FunThrill Seekers: Erotic Encounters

A novel about cross-dressing, social apathy, and seeing the best in people, a little too late.It started when I came home and found my bloody pointless stupid bastard boyfriend, Charlie, on my sofa, in my blue Lycra dress. He was having some sort of breakdown.It transpired that Charlie had been having an epiphany of sorts. The previous night, standing on his balcony, he had witnessed an attack – on a woman he'd just kicked out of his bed. Ahsen and shaken, on his way to work the next day, he had found a dead body in the train toilets and now here he was, in a dress, sobbing uncontrollably.I had been ready to dump Charlie once and for all – he was an unfaithful bastard (so was I, but not to the same extent). But he convinced me to run off with him to Devon for a week to sort his head out and I decided I owed him that much. Sizzling in the unlikely heatwave that week, everything changed between us, as we sucked on ice-creams naked on deckchairs, and hi-jacked an old people's bowling green. But despite the fact that our relationship had never been so strong and never meant so much to either of us, could we handle what was waiting for us back in London?